Surface enhanced Raman scattering of gold nanoparticles aggregated by a gold-nanofilm-coated nanofiber

Chang Cheng, Juan Li, Hongxiang Lei, and Baojun Li

Aggregation of metal nanoparticles plays an important role in surface enhanced Raman scattering (SERS). Here, a strategy of dynamically aggregating/releasing gold nanoparticles is demonstrated using a gold-nanofilm-coated nanofiber, with the assistance of enhanced optical force and plasmonic photothermal effect. Strong SERS signals of rhodamine 6G are achieved at the hotspots formed in the inter-particle and film-particle nanogaps. The proposed SERS substrate was demonstrated to have a sensitivity of 10−12 M, reliable reproducibility, and good stability.

DOI