Out-of-equilibrium forces between colloids

Indira Sriram and Eric M. Furst

Two colloidal probe particles are held with optical traps orthogonal to a uniformly flowing suspension of colloidal bath particles. Using confocal microscopy, the local bath suspension microstructure is characterized as a function of the probe separation and flow velocity. At sufficiently close separations, bath particles are excluded from passing between the probes, resulting in an asymmetric, non-equilibrium microstructure in which the major features are a depleted region between the probes and dense boundary layers along the surfaces that face away from the neighboring probe. As a consequence, the drag force acting on the probes is lower than that acting on a single probe and a net force pushes the probes together along their line of centers. The strength of the latter mutual force increases with increasing flow velocity. These experiments demonstrate that depletion-like forces can be induced between two particles by a non-equilibrium microstructure in a strongly driven suspension.

DOI