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Thursday, June 25, 2015

Synthesis and photo-postmodification of zeolite L based polymer brushes

Tim Buscher, Álvaro Barroso, Cornelia Denz and Armido Studer

A novel type of zeolite L/polymer hybrid material is presented. Polymer brush particles are generated using surface-functionalized zeolite L crystals as macroinitiators in controlled radical polymerization processes. Copolymerization of a photo-cleavable monomer and subsequent spin trapping of functionalized nitroxides under UV irradiation lead to a variety of highly functionalized zeolite L based core–shell particles.

DOI

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