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Wednesday, May 13, 2009

Optical force enhanced by plasmon resonance allowing position-sensitive synthesis and immobilization of single Ag nanoparticles on glass surfaces

Tamitake Itoh, Vasudevanpillai Biju, Mitsuru Ishikawa, Syoji Ito, and Hiroshi Miyasaka

Focused laser light in an aqueous solution of silver nitrate and disodium citrate allowed the synthesis and immobilization of single Ag particles on a glass surface. The as-synthesized Ag particles were free from aggregation. Rayleigh scattering spectra of the Ag particlesshowed a plasmon resonance band at ~490  nm. Analysis of the spectra revealed that the Ag particles have oblate-spindle shapes with ~30  nm diameter. The polarizability of the Ag nanoparticles demonstrated that soon after the formation of the particles at the focal point, optical force repels them out of the focal point and immobilizes on the glass surface. 

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